摘要
Ｃ６０（ＯＨ）ｎ在生物、医药、高分子材料等许多方面具有应用前景［１～３］，其合成对Ｃ６０衍生物的水溶液化学研究与合成新的有机化合物具有重要意义．利用各种不同的方法合成出羟基个数各不相同的Ｃ６０（ＯＨ）ｎ（ｎ＝１０～２６）已有报道［４～８］，但这些方法...
In this paper, we introduce a very rapid preparation method to produce water soluble C 60 derivativesfullerols by the reaction of C 60 with aqueous NaOH and H 2O 2 in the presence of tetrabutylammonium hydroxide(TBAH) as the catalyst, and the reaction is accelerated very much and the reaction time is shortened from 1￣3 d to 1￣3 h by adding H 2O 2 to replace O 2 in the air as the oxidant. FTIR, 1H NMR and MALDI TOF MS proved the multi hydroxy and C 60 cage structure of the products. The hydroxylated fullerere epoxidethe intermediate which is very easy to hydrolyze to become fullerols was obtained, and the formation mechanism of fulleols was put forward.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第6期858-860,共3页
Chemical Journal of Chinese Universities
基金
中国有色金属工业总公司高技术新材料项目资助
关键词
富勒醇
制备
羟基化
富勒烯环氧化物
C60衍生物
C 60 , Fullerols, Rapid preparation, Hydroxylated fullerene epoxides, Mechanism
