摘要
用电解法制备了有机－无机自由基盐（ＤＢＴＴＦ）６ＰＭｏ１２Ｏ４０·２Ｈ２Ｏ．用红外光谱、电子光谱和电子自旋共振谱进行了表征，测定了其磁化率、导电性和单晶的晶体结构．该晶体属三斜晶系，Ｐ１空间群．晶胞参数为ａ＝１．３７８７（７）ｎｍ，ｂ＝１．４２０４（２）ｎｍ，ｃ＝１．５７０２（２）ｎｍ，α＝１０４．５７０（８）°，β＝１０３．４１（２）°，γ＝９５．８０（２）°，Ｖ＝２．８５３（２）ｎｍ３，Ｚ＝１，Ｄｃ＝２．１４２Ｍｇ·ｍ－３，Ｒ＝０．０７２７．
Organic inorganic radical salt(DBTTF) 6PMo 12 O 40 \52H 2O was synthesized by electrocrystallization and characterized by IR spectrum, electronic spectrum and ESR technology. Its magnetic property, conductivity and crystal structure were determined. The title compound crystallized in a triclinic system with P 1 space group, a =1.378 7(7), b =1.420 4(2), c =1.570 2(2) nm, α =104.57(1)°, β =103.41(2)°, γ =95.80(2)°, V =2.853(2) nm 3, Z =1 and a final R =0.072 7.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第6期843-848,共6页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
自由基盐
钼磷杂多阴离子
DBTTF
电荷转移盐
Organic inorganic radical salt, Molybdophosphateheteropoly anion, Dibenzotetrathiofulvalene, Crystal structure
