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CO对CO_2加氢合成甲醇的影响 被引量:2

Effect of CO on Methanol Synthesis from CO_2 Hydrogenation
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摘要 The effect of CO on methanol synthesis from CO2 hydrogenation over Cu-Zn-Al cat-alysts have been investigated by TPSR-MS techniques and evaluated by testing the catalytic per-formance. The results indicated that CO can Occupy part of CO2 adsorption site on the catalystsurface to restrain the reverse water gas shift reaction and promote methanol synthesis in CO2hydrogenation . Therefore it inereases the Inethanol selectivity and yield from CO2 hydrogenation. The effect of CO on methanol synthesis from CO2 hydrogenation over Cu-Zn-Al cat-alysts have been investigated by TPSR-MS techniques and evaluated by testing the catalytic per-formance. The results indicated that CO can Occupy part of CO2 adsorption site on the catalystsurface to restrain the reverse water gas shift reaction and promote methanol synthesis in CO2hydrogenation . Therefore it inereases the Inethanol selectivity and yield from CO2 hydrogenation.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1998年第3期275-277,共3页 Acta Physico-Chimica Sinica
基金 香港研究基金!RGC/96-97/02 厦门大学固体表面物理化学国家重点实验室资助
关键词 加氢 合成 甲醇 一氧化碳 二氧化碳 CO_2 hydrogenation, Synthesis methanol, Effect of CO, High selectivity of methanol
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参考文献2

  • 1李基涛,天然气化工,1997年,32卷,2期,39页
  • 2蔡启瑞,碳一化学中的催化作用,1995年,1页

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