摘要
合成了１６个β－烷氧羰基乙基三氯化锡与二甲基亚砜、Ｎ－氧化吡啶、吡啶等单齿配体的配合物，经过元素分析、ＩＲ、＾１Ｈ ＮＭＲ、ＴＧ－ＤＴＡ等表征了其结构。报道了β－烷氧羰基乙基三氯化锡配合物和醇的酯交换反应，提出了其可能的反应机理。
Sixteen complexes of β - alkoxycarbonylethyltintrichlorides with monodentate ligands such as dimethylsulfoxide, pyridineN - oxide and pyridine were synthesized and characterized by elemental analysis, IR, 1H NMR and TG - DTA. The transesterification of β -methoxycarbonylethyltin trichloride complexes with an alcohol was reported and the possible mechanism was suggested.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1998年第1期37-42,共6页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金
关键词
有机锡配合物
合成
酯交换反应
β-alkoxycarbonylethyltin trichloride, organotin complex, synthesis, transesterification reaction
