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一个新颖的二重互穿的三维无机．有机杂化化合物[Cd(C5H3N2O2)2(H2O)]n的合成和晶体结构

Synthesis and Crystal Structure of a Two-Fold Three-Dimesional Inorganic-Organic Hybrid Complex [Cd(C_5H_3O_2)_2(H_2O)]_n
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摘要 A three-dimensional two-fold inorganic-organic hybrid complex:[Cd(C5H3O2)2(H2O)]n(1),was synthesized under mild hydrothermal condition,and the X-ray crystal structure analysis was used to determined the structure.The complex crystallizes in the orthorhombic space group Pbca,with a=1.147 6(2) nm,b=1.211 1(2) nm,c=1.750 3(4) nm,V=2.432 6(8) nm3,Z=8,R1=0.032 3,wR2=0.134 3. A three-dimensional two-fold inorganic-organic hybrid complex： [Cd（C5H3O2）2（H2O）], （1）, was synthesized under mild hydrothermal condition, and the X-ray crystal structure analysis was used to determined the structure. The complex crystallizes in the orthorhombic space group Pbca, with a=1.147 6（2） nm, b=1.211 1 （2） nm, c=1.750 3（4） nm, V=2.4326（8） nm^3, Z=8, R1=0.032 3, wR^2=0.1343. CCDC： 714446.
作者 张鹏 王恩波 邢长宇 康平利 李凯
机构地区 辽宁大学化学院 东北师范大学化学学院
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2009年第3期560-562,共3页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.20371011)
关键词 二重互穿 三维 水热合成 晶体结构 two-fold interpenetration three-dimensional hydrothermal synthesis crystal structure
分类号 O614.242 [理学—无机化学]
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无机化学学报
2009年 第3期

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