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可充碱锰电池用锰的钙钛矿氧化物研究

Research on Peroskite Type Oxides with Manganese for Rechargeable Alkaline Cell
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摘要 锰的钙钛矿氧化物通过共沉淀法制备。用X射线粉末衍射法测定其晶体结构,用恒流充放电和循环伏安法研究了钙钦矿氧化物Bi_(0.1)Ca_(0.9)。MnO_3在碱性溶液中的可充性,实验结果表明Bi_(0.1)Ca(0.9)MnO_3作为碱性可充阴极材料具有良好的可逆性,并可深度充放电而保持结构稳定。 Peroskite-type oxide Bi0.1Ca0.9MnO3 was prepared by coprecipitation method,its crystal form Was determined by XRD and its rechargeability was studied by cyclic voltammetry and galvanostatic charge - discharge method. The experimental results indicated that peroskite - type oxide Bi0.1Ca0.9MnO3 showed excellent rechargeability in deep discharge regions.
作者 吴智远
机构地区 武汉大学化学系
出处 《电池》 CAS CSCD 北大核心 1998年第1期12-14,共3页 Battery Bimonthly
关键词 钙钛矿氧化物 碱锰电池 可充性 锰电池 Peroskite-type Oxides Alkaline Manganese Cell Rechargeability
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参考文献2

  • 1T. Esaka,M. Kamata,M. Ohnishi. Control of oxygen deficiency in Ca1?x La x MnO3?δ and its cathodic properties in alkaline solution[J] 1996,Journal of Applied Electrochemistry(4):439~442
  • 2T. Esaka,H. Morimoto,H. Iwahara. Nonstoichiometry in perovskite-type oxide Ca1?x Ce x MnO3?δ and its properties in alkaline solution[J] 1992,Journal of Applied Electrochemistry(9):821~824

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