摘要
A mono-complex has been synthesized by the reaction of 2,6-dicarboxamido-(2-pyridyl)-pyridine(H2pdcap) and CuCl2.X-ray diffraction technique reveals that the central Cu(II) ion lies in a distorted trigonal bipyramid geometry.The crystal is assigned to triclinic with space group Pī.The cell parameters are:a=0.8614(17);b=1.0621(2);c=1.0647(2);α=76.65(3)°;β=82.46(3)°;γ=82.58(3)°.The powder SHG effect of the title complex is 1.3 times than that of carbamide.
A mono- complex has been synthesized by the reaction of 2,6 -dicarboxamido- （2 -pyridyl ） -pyridine （H2 pdcap ） and CuCl2. X- ray diffraction technique reveals that the central Cu（Ⅱ） ion lies in a distorted trigonal bipyramid geometry. The crystal is assigned to triclinic with space group Pi. The cell parameters are ： α = 0.8614 （ 17 ） A; b = 1. 0621 （2） A;c = 1. 0647 （2） A ; α= 76.65 （3） °;β = 82.46 （ 3 ）°;γ = 82.58 （3）°. The powder SHG effect of the title complex is 1.3 times than that of carbamide.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2009年第2期225-228,共4页
Chemical Research and Application
基金
国家自然科学基金项目(No.20671082和20801048)资助
关键词
铜配合物
倍频效应
量化计算
Cu coordination complex
SHG effect
quantum - chemical calculation
