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尿酸在聚亚甲基蓝修饰金电极上的电化学及电化学动力学性质 被引量：3

Electrochemical behaviors of uric acid at gold electrode modified with polymethylene blue and its electrochemical kinetics
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摘要 The electrochemical properties of gold electrode(PMB/Au) modified with polymethylene blue(PMB) and the electrochemical behaviors of UA at PMB/Au were studied.The kinetics parameters were determined.PMB/Au exhibited a significant catalytic effect for the oxidation of Uric acid(UA).The oxidation peak potential shifted 70mV negatively and the peak current increased greatly for UA at PMB/Au comparing with the bare Au electrode.The kinetic parameters such as the electron transfer coefficient and the reaction rate constant for catalytic oxidation of UA on PMB/Au were evaluated,respectively. The electroehemieal properties of gold electrode （PMB/Au） modified with polymethylene blue （PMB） and the dectrochemical behaviors of UA at PMB/Au were studied. The kinetics parameters were determined. PMB/Au exhibited a significant catalytic effect for the oxidation of Uric acid （UA）. The oxidation peak potential shifted 70mY negatively and the peak current increased greatly for UA at PMB/Au comparing with the bare Au electrode. The kinetic parameters such as the electron transfer coefficient and the reaction rate constant for catalytic oxidation of UA on PMB/Au were evaluated, resoectively.
作者 马艳蓉 李力 高作宁
机构地区 北方民族大学 宁夏大学能源化工重点实验室化学化工学院
出处 《化学研究与应用》 CAS CSCD 北大核心 2009年第2期207-210,共4页 Chemical Research and Application
基金 北方民族大学科研项目(2007Y040)资助
关键词 尿酸 聚亚甲基蓝 修饰电极 电化学性质 uric acid polymethylene blue modified electrode electrochemical behaviors
分类号 O657 [理学—分析化学]
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参考文献16

  • 1Luo J, Zhang M, Pang D. Selective and sensitive determination of uric acid at DNA-modified graphite powder microelectrodes [ J ]. Sensors and Actuators B, 2005,16:358-362.
  • 2孙延一.尿酸在多壁炭纳米管修饰电极上的伏安法测定[J].理化检验（化学分册）,2003,39(7):381-383. 被引量：11
  • 3Lin X Q,Jin G P. Monolayer modification of glassy carbon electrode by using propionylcholine for selective detection of uric acid [ J ]. Electrochimica Acta, 2005, 50:3210-3216.
  • 4Palraj K,Suresh D, Abraham J S. Uric acid determination in the presence of ascorbic acid using self-assembled modified gold electrodes [ J ]. Anal Biochem, 2006,357 : 188-193.
  • 5Zare H R, Nasirizadeh N, Ardakani M M. Electrochemical properties of a tetrabromo-p-benzoquinone modified carbon paste electrode. Application to the simultaneous determination of ascorbic acid, dopamine and uric acid [ J]. J Electroanal Chem ,2005,577:25-33.
  • 6Lin X, Li Y. Monolayer covalent modification of 5- hydroxytryptophan on glassy carbon electrodes for simultaneous determination of uric acid and ascorbic acid [ J ]. Electrochimica Atca ,2006,51:5794-5801.
  • 7Zare H R, Memarzadeh F, Ardakani M M, et al. Norepinephrine-modified glassy carbon electrode for the simultaneous determinatin of ascorbic acid and uric acid [ J ]. Electrochimica Acta ,2005,50:3495-3502.
  • 8蔡超,高作宁.阳离子表面活性剂溶液的临界胶束浓度及扩散系数[J].化学研究与应用,2004,16(5):643-645. 被引量：15
  • 9姚慧琴,高作宁.用氯离子电极同时测定阳离子表面活性剂的CMC及反离子缔合度[J].化学研究与应用,2004,16(4):543-544. 被引量：9
  • 10马艳蓉,高作宁.甲苯胺蓝在SDS胶束中的电化学行为研究[J].化学研究与应用,2006,18(8):912-916. 被引量：5

二级参考文献41

共引文献47

同被引文献57

  • 1张建明,宋远志.5种酚的电化学行为及其反应活性的理论计算[J].华中师范大学学报（自然科学版）,2004,38(4):472-475. 被引量：9
  • 2倪永年,齐正保.化学计量学速差动力学光谱法同时测定盐酸氯丙嗪和盐酸异丙嗪[J].光谱学与光谱分析,2006,26(7):1364-1367. 被引量：12
  • 3李云龙,谢青季,姚守拙.EQCM监测高氯酸溶液中金电极上苯二酚电荷转移配合物的沉积[J].应用化学,2007,24(6):628-631. 被引量：2
  • 4NAGARAJA P, VASANTHA R A, SUNITHA K R. A sensitive and selective spectrophotometric estimation of catechol derivatives in pharmaceutical preparations[ J]. Talanta, 2001, 55 (6) : 1039 - 1046.
  • 5PENNER N A, NESTERENKO P N, RYBALKO M A. Use of hypercrosslinked polystyrene for the determination of pyrocatechol, resorcinol, and hydroquinone by reversed-phase HPLC with dynamic on-line preconcentration [ J ]. J Anal Chem, 2001, 56(10): 934-939.
  • 6ASAN A, ISILDAK I. Determination of major phenolic compounds in water by reversed phase liquid chromatography after pre-column derivatization with benzoyl chloride[ J]. J Chromatogr: A, 2003, 988(1) : 145 -149.
  • 7ROSANGELA M, DE CARVALHO, CESAR M, et al. Simultaneous determination of phenol isomers in binary mixtures by differential pulse voltammetry using carbon fibre electrode and neural network with pruning as a multivariate calibration tool[J]. Anal Chim Aeta, 2000, 420(1) : 109 -121.
  • 8DING Yaping, LIU Weili, WU Qingsheng, et al. Direct simultaneous determination of dihydroxybenzene isomers at C- nanotube-modified electrodes by derivative voltammetry [ J]. J Electroanal Chem, 2005, 575 ~2) : 275 -280.
  • 9WANG Huaisheng, HUANG Deqian, LIU Renmin. Study on the electrochemical behavior of epinephrine at a poly (3- methylthiophene)-modified glassy carbon electrode[J]. J Electroanal Chem, 2004, 570( 1 ) : 83 -90.
  • 10CAI Qiantao, KHOO S B. Poly(3, 3'-diaminobenzidine) film on a gold electrode for selective preconcentration and stripping analysis of selenium(Ⅳ) [J]. Anal Chem, 1994, 66(24) : 4543 -4550.

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化学研究与应用
2009年 第2期

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