摘要
基于DebyeHeckel强电解质溶液活度系数理论,反应速度的活化络合物理论,以双稳态跳跃的简化动力学模型研究了非理想性对BZ反应振荡振幅的影响,发现振幅随着离子强度增加而增大,并得到了实验的证实.
On the basis of the DebyeHuckel activity coefficient theory of electrolyte solution,the activated complex theory of reaction rate and the bistability jump theory the influence of nonideality on the amplitude of BelousovZhabotinskii oscillating reaction is investigated.It is found that the amplitude increases with the ionic strength increase,and that the expermental result is in agreement with the theorefical analysis.
出处
《四川大学学报(自然科学版)》
CAS
CSCD
北大核心
1998年第1期89-92,共4页
Journal of Sichuan University(Natural Science Edition)
基金
国家自然科学基金
关键词
BZ反应
非理想性
化学振荡幅值
电解质溶液
BZ oscillating reaction,oregonator model,nonideality,chemical oscillation amplitude