摘要
四硫富瓦烯(TTF)及其衍生物由于具有特殊的结构和性质,在分子开关、分子传感器、光信息存储和非线性光学等领域显示出诱人的应用前景.综述了近几年TTF及其衍生物在分子开关领域的最新研究进展.
Tetrathiafulvalene （TTF） and its derivatives can be reversibly transformed into the radical cation TTF^2＋ and dication TTF^2＋ through either chemical or electrochemical oxidation. By using of this feature, TTF and its derivatives have been widely investigated for their potential use in molecular switches, molecular sensors, optical information storage and nonlinear optics etc. This article reviews the recent progress in TTF and its derivatives as molecular switches such as fluorescence switch, photochromism switch, chiral switch and supramolecular switch.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2009年第1期34-43,共10页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.20571029,20671038)
江苏省科技厅自然科学基金(No.BK2006061)资助项目
关键词
四硫富瓦烯
合成
分子开关
分子识别
tetrathiafulvalene
synthesis
molecular switch
molecular recognition
