期刊文献+

紫外光下Ag_3VO_4催化降解亚甲基蓝的研究 被引量:3

Photocatalytic Degradation of Methylene Blue over Ag_3VO_4 under UV Light Irradiation
在线阅读 下载PDF
导出
摘要 通过共沉淀法合成Ag3VO4,紫外光下以亚甲基蓝模拟染料废水为对象进行光催化降解实验,分析考察了催化剂的投加量、亚甲基蓝的初始浓度和通气量对光催化降解的影响。并用XRD,SEM,TEM和UV-vis漫反射对Ag3VO4的结构进行了表征。实验结果表明,紫外光下Ag3VO4降解亚甲基蓝有良好的催化活性,当催化剂用量为0.3g/L,通气量为2L/min以及初始浓度为10mg/L时,120min后亚甲基蓝的降解率达到98%。 Ag3VO4 power was synthesized by precipitation method. Methylene blue was selected to simulate organic dye wastewater which was treated by photocatalytic oxidation using Ag3VO4 as photocatalyst under UV light irradiation. Effects of catalyst dosage, initial concentration of methylene blue and air flow rate on photocatalytic reactions were studied as well. Ag3VO4 powers were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy(TEM) and UV-vis diffuse reflectance spectra. Experiments indicated that Ag3VO4 showed high photocatalytic activity to photodegrade methylene blue under UV light irradiation. When the catalyst dosage was 0.3g/L, initial concentration of methylene blue was 10mg/L and air flow rate was 2L/min, the degradation rate of methylene blue was 98% after 120minutes.
出处 《环境科学与技术》 CAS CSCD 北大核心 2009年第2期42-45,共4页 Environmental Science & Technology
基金 镇江社会发展基金项目资助(SH2006069) 江苏大学人才启动基金项目资助(04JDG044)
关键词 Ag3VO4 紫外光 降解 亚甲基蓝 Ag3VO4 UV light degradation methylene blue
  • 相关文献

参考文献13

  • 1Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode [J]. Nature, 1972,238 (5358) : 37-38.
  • 2Takeda K, Fujiwara K. Characteristics on the determination of dissolved organic nitrogen compounds in natural waters using titanium dioxide and platinized titanium dioxide mediated photocatalytic degradation [J]. Water Res, 1996, 30 (2) : 323-330.
  • 3Balasubramanian G, Dionysiou D D, Suidan M T, et al. Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water[J]. Appl Catat, B: Environ, 2004, 47(2): 73-84.
  • 4Khodja A A, Sehili T, Pilichowski J F, et al. Photocatalytic degradation of 2-phenylphenol on TiO2 and ZnO in aqueous suspensions[J]. J Photochem Photobiol, A: Chem, 2001, 141(2-3) : 231-239.
  • 5Zou Z G, Ye J H, Sayama K, et al. Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst[J]. Nature, 2001, 414(6864) : 625-627.
  • 6Kohtani S, Koshiko M, Kudo A, et al. Photocatalytic degradation of 4-n-nonylphenol under irradiation from solar simulator: Comparison between BiVO4 and TiO2 photocatalysts[J]. Chem Lett, 2002,7( 1 ) : 660-661.
  • 7Kohtani S, Koshiko M, Kudo A, et al. Photodegradation of 4-alkylphenols using BiVO4 photocatalyst under irradiation with visible light from a solar simulator[J]. Appl Catal B: Environ, 2003, 46(3): 573-586.
  • 8Kato H, Kudo A. New tantalate photocatalysts for water decomposition into H2 and O2[J]. Chem Phys Lett, 1998, 295 (5-6) : 487-492.
  • 9Tang J, Zou Z, Ye J. Photocatalytic degradation of methylene blue on CaIn2O4 under visible light irradiation[J]. Chem Phys Lett, 2003, 382(1-2): 175-179.
  • 10Zhou L, Wang W Z, Zhang L S. Ultrasonic-assisted synthesis of visible-light-indyced Bi2MO6 (M=W,Mo) [J]. J Mol Catal A: Chem, 2007,268(1-2) : 195-200.

同被引文献36

  • 1秦好丽,古国榜,柳松,吴松平.溶胶凝胶法制备氮掺杂二氧化钛及其可见光活性的研究[J].太阳能学报,2007,28(4):363-367. 被引量:18
  • 2Silva C G, Faria J L. Photochemical and photoeatalytic degradation of an azo dye in aqueous solution by UV irradiation [J]. Journal of Photochemistry and Photobiology A :Chemistry,2003,155 (1/2/3): 133-143.
  • 3Chong Mengnan,Jin Bo, Chow C W K,et al. Recent developments in photocatalytic water treatment teehnology:A review [J]. Water Re- search, 2010,44 ( 10 ) : 2997 -3027.
  • 4Li Youji, Ma Mingyuan, Wang Xiaohua, et al. Preparation of cerium doped titania macroporous films by a sol-gel spin coating using polypropylene glycol(PPG) as pore creating agent:Effects of Ce ions, PPG and calcination on photocatalytic activity [J ]. Surface and Coatings Technology, 2010,204 (9/10) : 1353-1358.
  • 5Wang Ying, Wang Yan, Meng Yanling, et al. A highly efficient visible-light-activated photocatalyst based on bismuth- and sulfur- codoped TiO2[J]. J. Phys. Chem. C ,2008,112(17) :6620- 6626.
  • 6Yu Jiaoxian, Liu Suwen, Xiu Zhiliang, et al. Combustion synthesis and photocatalytic activities of Bi3+-doped TiO2 nanocrystals[J].Journal of Alloys and Compounds, 2008,461 ( 1/2 ) : L17-L19.
  • 7Sohrabi M R, Ghavami M. Photocatalytic degradation of Direct R23 dye using UVfriO2:Effect of operational parameters [J ]. Journal of Hazardous Materials,2008,153(3) : 1235-1239.
  • 8HU X X,HU C.Preparation and visible-light photocatalytic activity of Ag3VO4 Powders[J].J Solid State Chem,2007,180(2):725-732.
  • 9HU X X,HU C,QU J H.Preparation and visible-light activity of silver vanadate for the degradation of pollutants[J].Mater Res Bull,2008,43(11):2986-2997.
  • 10HUANG C M,PAN G T,LI Y C M,et al.Crystalline phases and photocatalytic activities of hydrothermal synthesis Ag3VO4and Ag4V2O7under visible light irradiation[J].Appl Catal A Gen,2009,358(2):164-172.

引证文献3

二级引证文献11

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部