摘要
应用电位扫描法制备3种铂与氢钨青铜(HxWO3)的复合电极,即铂上沉积氢钨青铜(HxWO3/Pt),氢钨青铜上沉积铂(Pt/HxWO3)及铂和氢钨青铜共沉积(Pt-HxWO3).测试结果表明,氢钨青铜能显著提高铂电催化对氧还原的活性,其中以复合电极Pt/HxWO3的电催化活性最高,这可能是因为在玻碳基底上先电沉积氢钨青铜再电沉积铂增加了铂的有效比表面,该电极制备为减少铂用量提供一条有效途径.
Three composite electrodes of platinum with hydrogen tungsten bronze （Hx WO3 ）were prepared by voltammetry： hydrogen tungsten bronze deposited on platinum （HxWO3/Pt） ;platinum deposited on hydrogen tungsten bronze （ Pt/HxWO3 ） and codeposited platinum and hydrogen tungsten bronze （ Pt-HxWO3 ）. The eletro- catalytic activities of three electrodes toward oxygen reduction reaction were studied. It is found that the catalytic activity of platinum can be improved by introducing with hydrogen tungsten bronze. Among these composite electrodes Pt/HxWO3, and the electrode shows the best eletro-catalytic activity toward oxygen reduction reaction, hence, provides a new way for reducing loading of noble metal in the application for fuel cell.
出处
《电化学》
CAS
CSCD
北大核心
2008年第4期398-401,共4页
Journal of Electrochemistry
基金
国家自然科学基金(20573039)资助
关键词
氧还原
催化
氢钨青铜
铂
复合
oxygen reduction
catalysis
hydrogen tungsten bronze
platinum
composite
