摘要
在Cd（ClO4）_2·6H2O存在下，三（2－氨基乙基）胺（tren）与2，6－二甲酰基－4－氯苯酚钠进行[2＋3]希夫碱缩合合成了一个全新的双核镉（Ⅱ）穴合物。穴合物的晶体结构，光谱表征数据及摩尔电导表明，穴合物中的两个镉离子通过三个酚氧基桥连。每个镉离子位于七配位环境中（N4O3），其配位构型是一个带帽的三角双锥结构。
A new bicadmium (Ⅱ) Cryptate was synthesized by [2+3] Schiff base condensation of tris (2-aminoethy) amine with sodium 2, 6-diformyl-4-chlorophenolate in the presence of Cd (ClO4)2·6H2O. The Crystal structure, characterization of spectra and molar conductivity showed that two cadmium (Ⅱ) atoms were bridged by threc phenoxy oxygen atoms. Each cadmium(Ⅱ) is located in a seven coordination environment (N4O3). The Coordination geometry around the Cd (Ⅱ) is a capped triangular prism.
出处
《淮海工学院学报（自然科学版）》
CAS
1997年第1期63-67,共5页
Journal of Huaihai Institute of Technology:Natural Sciences Edition
关键词
镉穴合物
晶体结构
酚氧桥基
双核配合物
席夫碱
cadmium(Ⅱ) cryptate, crystal structure, phenoxy oxygen bridge, binuclear complex
