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Pybox-hm的Co(Ⅱ)、Ni(Ⅱ)、Zn(Ⅱ)、Cu(Ⅱ)配合物的合成、表征和电化学性质

Cobalt(Ⅱ),nickel(Ⅱ),zinc(Ⅱ)and copper(Ⅱ) complexes containing Pybox-hm ligand:synthesis,spectral and electrochemical properties
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摘要 在室温下用手性配体2,6-二(4R-羟甲基-4,5-二氢唑)吡啶(Pybox-hm)和无机金属盐合成了Co(Ⅱ)、Ni(Ⅱ)、Zn(Ⅱ)和Cu(Ⅱ)配合物,分别用红外光谱、紫外光谱、离子质谱、元素分析等对其进行了表征,并用摩尔电导率和循环伏安法研究了其电化学性质。 The Co（Ⅱ ）,Ni（ Ⅱ ）,Zn（ Ⅱ ） and Cu（ Ⅱ ） complexes were synthesized by reacting 2, 6-his （4R-hydroxymethyl-oxazolyl）pyridine（ Pybox-hm ） with the corresponding metal salts in anhydrous ethanol at room temperature. They were characterized for the first time by FT-IR spectroscopy, UV-Vis spectroscopy, ESI-MS, elementary analysis, molar conductivity measurements and electrochemical studies, respectively.
作者 钟丽琴 唐瑞仁
机构地区 中南大学化学化工学院
出处 《化学试剂》 CAS CSCD 北大核心 2008年第11期833-835,838,共4页 Chemical Reagents
关键词 PYBOX 配合物 合成 表征 Pybox metal complex synthesis characterization
分类号 O614.8 [理学—无机化学] O626.1 [理学—有机化学]
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参考文献12

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二级参考文献73

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化学试剂
2008年 第11期

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