摘要
在常温常压下,以氧气为氧化剂,溴化氢和亚硝酸叔丁酯为催化剂,高选择性地催化氧化了一系列硫醚.该非过渡金属催化体系具有操作方便,反应条件温和,产品易于分离,产物收率高(90%～96%)等优点.
At room temperature and atmospheric pressure, using O2 as an oxidant, HBr and tert-butyl nitrite as catalysts, selective oxidation of a broad range of sulfides was achieved. The transition-metal-free system exhibits the advantages of simple operations, mild reaction conditions, easy separation of products and high yields （90%-96%）.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2008年第11期1978-1981,共4页
Chinese Journal of Organic Chemistry
