摘要
二甲基硅烯与含烯丙基甲醚结构的化合物1—5的反应具有良好的化学和区域选择性。产物是双键经过重排的取代烯丙基二甲基甲氧基硅烷6—10,该产物可进行一系列亲电取代反应。
The reaction of dimethylsilylene with the compounds containing allylmethyl ether moieties (1—5) gave allyldimethylmethoxy siloxane (6—10) with very good chemo- and regio-selectivities. The rearrangement of allylic double bond took placed in the course of these reaction. 6—12 are able to undergo a lot of electrophilic substitution reaction.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1990年第5期516-520,共5页
Acta Chimica Sinica
