摘要
本文利用Konig-Kremer配体场能级图,通过吸收谱和谱图比较,定出了有机配合物(PAP6Me)Co(NCS)_2的空间构型及光谱参量。计算的磁矩和观测结果一致。由此说明,这种方法对分析某些较复杂的有机(或无机)配合物的光学及顺磁性质很可能是有效而简便的。
By using the ligand field energy diagrams of Konig—Kremer and making a comparison between absorption spectra and energy diagrams, the space stereo configuration and the spectral parameters of organic complex (PAP6Me)Co(NCS)_2 have been determined. The magnetic moment can be obtained by using known spectral parameters. The calculated value of magnetic moment is in agreement with observed result by Thompson et al. The spectra properties and magnetic properties of this organic complex can be connected with this complex's space structure and it's relation of bonds. This method used by us has the better effect for analysis of spectral property and optical-magnetic property of some organic (or inorganic) complexes of transitonal metal.
基金
国家科学基金
