摘要
As an improvement of reported Y2O2S:Tb^3+, a white-light long-lasting phosphor: Y2O2S:Tb^3+, Sm^3+ was prepared by the solid-state reaction. The photo-luminescence spectra showed that the position and shape of Tb^3+ and Sm^3+ emissions under UV excitation were similar in this host, which ensured a stable white emission color (daylight standard of IEC) under different excitations. The decay curves of co-doped samples indicated that the decay times of emissions of the two ions were close. The thermo-luminescence measurement suggested that the traps created by the doped Sm^3+ ions were helpful to postpone the white afterglow of co-doped samples. Therefore, the function of co-doped Sm^3+ ions was confirmed as improving the white emission colors of samples and acting as new trap centers.
As an improvement of reported Y2O2S:Tb^3+, a white-light long-lasting phosphor: Y2O2S:Tb^3+, Sm^3+ was prepared by the solid-state reaction. The photo-luminescence spectra showed that the position and shape of Tb^3+ and Sm^3+ emissions under UV excitation were similar in this host, which ensured a stable white emission color (daylight standard of IEC) under different excitations. The decay curves of co-doped samples indicated that the decay times of emissions of the two ions were close. The thermo-luminescence measurement suggested that the traps created by the doped Sm^3+ ions were helpful to postpone the white afterglow of co-doped samples. Therefore, the function of co-doped Sm^3+ ions was confirmed as improving the white emission colors of samples and acting as new trap centers.
基金
the National Natural Science Foundation of China (10404028)
Young Scientists Innovation Foundation of Fujian Province (2007F3027)