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纳米SnO_2及分子筛封装纳米SnO_2簇的氢还原研究 被引量:1

Studies on Hydrogen Reduction of nm SnO_2 and Zeolite Entrapped nm SnO_2 Clusters
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摘要 研究了液相法制备的纳米SnO2和分子筛封装的纳米SnO2簇(Cluster)的氢还原情况,实验发现,与普&SnO2微粒相比,纳米SnO2超微粒和分子筛封装的纳米SnO2簇的氢还原起始温度可降低100℃~150℃,氢还原起始表观活化能大小为SnO2微粒>纳米SnO2微粒>分子筛封装纳米SnO2簇。 The reaction of hydrogen reduction of nm SnO2 (10 nm) prepared by liquid-phase method and zeolite entrapped nm SnO2 clusters is studied. The reduction temperature of nm SnO2 and nm SnO2 clusters is about 100~150℃ lower than that of common SnO2, and the sequence of Ea of hydrogen reduction is as follows: common SnO2>nm SnO2>nm Sno2 clusters.
出处 《浙江工业大学学报》 CAS 1997年第2期137-143,共7页 Journal of Zhejiang University of Technology
关键词 二氧化锡 分子筛 还原 纳米陶瓷 nm Tin dioxide Zeolite cluster Hydrogen reduction
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  • 1郭景坤,徐跃萍.纳米陶瓷及其进展[J].硅酸盐学报,1992,20(3):286-291. 被引量:87
  • 2G. B. Schaffer,P. G. McCormick. Displacement reactions during mechanical alloying[J] 1990,Metallurgical Transactions A(10):2789~2794
  • 3G. B. Schaffer,P. G. McCormick. Combustion and resultant powder temperatures during mechanical alloying[J] 1990,Journal of Materials Science Letters(9):1014~1016

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