摘要
Zr-2.5Nb合金经β相水淬及冷轧变形后,再经过580℃/5h和650℃/2h的热处理,在静态高压釜中进行550℃/25MPa超临界水腐蚀实验。用电子显微镜研究了腐蚀前、后合金基体的显微组织。结果表明在550℃/25MPa超临界水中腐蚀到一定程度后,合金基体内会形成氢稳定的β-Zr相,同时合金元素Nb扩散进入该相,形成富Nb/H的β-Zr相。该相在降温过程中发生分解,形成ZrHx、α-Zr和Nb含量不同的Zr-Nb相组织。
The corrosion behavior for Zr-2.5Nb specimens heat-treated at 580 ℃/5 h and 650 ℃/2 h respectively after β-quenching and cold rolling have been investigated in 550 ℃/25 MPa supercritical water (SCW) by autoclave tests. The scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM) equipped with an energy dispersion spectroscopy (EDS) were employed for examining the matrix microstructure of the specimens before and after corrosion tests. It was noted that the microstructure of the matrix for the alloy specimens were drastically changed after corrosion testing for a certain period. It is considered that H-stabilized β-Zr were formed during corrosion testing at 550 ℃, and at the same time the Nb alloying element diffused into the β-Zr to form Nb/H-enriched β-Zr, which decomposed to ZrHx, α-Zr and Nb-enriched Zr-Nb phases as the corrosion temperature decreased.
出处
《稀有金属材料与工程》
SCIE
EI
CAS
CSCD
北大核心
2008年第10期1815-1818,共4页
Rare Metal Materials and Engineering
基金
上海市重点学科建设资助(T0101)
国家自然科学基金(50571056)资助
关键词
Zr-2.5Nb合金
超临界水
吸氢
相变
Zr-2.5Nb alloy
supercritical water
corrosion
phase transformation