摘要
合成了5种不对称冠醚碲碳菁染料.对合成关键中间体冠醚苯并碲唑所用的4-硝基苯并15-冠-5的还原酰化方法进行了改进,比较和研究了杂原子在同一主族的4个菁染料的可见吸收光谱,计算了它们的“Brooker偏差”
Five asymmetric crown telluracarbocyanines were prepared. The visible absorption spectra and the “Brooker diviation” of four of them have been studied. The method of reduction and acylation of 4nicrobenzo15crown5 has been improved, making the synthesis of the asymmetric crown ether telluracarbocyanine dyes quite convenient and easy.
出处
《应用化学》
CAS
CSCD
北大核心
1997年第4期10-13,共4页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金