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金属配合物(pq)_2Ir(N-phMA)发光材料的合成及光谱性质

Synthesis and Spectral Property of a Phosphorescent Luminescence Material(pq)_2Ir(N-phMA)
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摘要 设计出一种酰胺类金属铱有机配合物磷光电致发光材料,该材料是以2-苯基喹啉(pq)为主配体,N-苯基甲基丙烯酰胺(N-phMA)为辅助配体的金属配合物(pq)2Ir(N-phMA)。该化合物的结构由核磁,红外表征确定,它在586nm处的强荧光发射,表明它是一种可用于OLED的黄光发光材料。 An electrophosphorescent Ir complex with 2-phenyl quinoline as cyclometalate ligand and methacrylamide as ancillary ligand has been synthesized and Its structure was determined by HNMR and IR. The complex was observed high fluorescence at 586 nm, which prove its potential application in OLED.
出处 《光谱实验室》 CAS CSCD 2008年第5期893-896,共4页 Chinese Journal of Spectroscopy Laboratory
基金 国家自然科学基金(No20571033) 新世纪优秀人才支持计划(NCET-06-0483)支持
关键词 2-苯基喹啉 N-苯基甲基丙烯酰胺 光谱性质 铱配合物 2-Phenyl Quinoline, N-Phenyl Methacrylamide, Spectroscopy Property, Ir Complex.
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  • 1Tang C W,Vanslyke S A. Organic Eleetrolumineseent Diodes[J]. Appl. Phys. Lett. , 1987,51(12) :913-915.
  • 2Gu G,Sben Z,Burrows P E et al. Transparent Flexible Organic Light-Emitting Devices[J]. Adv. Mater. , 1997,9(9) :725-728.
  • 3You Y M, Park S Y. lnter-Ligand Energy Transfer and Related Emission Change in the Cyclometalated Heteroleptic Iridium Complex: Facile and Efficient Color Tuning over the Whole Visible Range by the Ancillary Ligand Structure[J]. J. Am. Chem. Soc., 2005.127(36) : 12438-12439.
  • 4Lamansky S, Djurovich P,Murphy D et al. Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes [J]. Inorg. Chem. , 2001,40(7): 1704-1711.
  • 5Li J, Djurovich P, Alleyne B D et al. Synthetic Control of Excited-State Properties in Cyclometalated Ir (Ⅱ) Complexes Using Ancillary Ligands[J]. Inorg. Chem. , 2005,44(6) : 1713-1727.
  • 6Sprouse S, King K A, Spenane P Jet al. Photophysical Effects of Metal-Carbon. Sigma. Bonds in Ortho-Metalated Complexes of Iridium(Ⅲ) and Rhodium(Ⅲ)[J]. J. Am. Chem. Soc. , 1984,106(22):6647-6653.
  • 7Nonoyama M. Benzo[h]quinolin-10-yl-N Iridium(Ⅱ) Complexes[J]. Bull. Chem. Soc.Jpn. , 1974,47(3): 767-768.
  • 8Li J, Djurovich P I, Alleyne B D et al. Synthetic Control of Excited-State Properties in Cyclometalated Ir (Ⅲ) Complexes Using Ancillary Ligands[J]. Inorg. Chem. , 2005,44(6) : 1713-1727.
  • 9Kawamura Y,Goushi K,Brooks J et al. 100% Phosphorescence Quantum Efficiency of Ir(Ⅱ) Complexes in Organic Semiconductor Films[J]. Appl. Phys. Lett., 2005,86(7) :071104.

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