摘要
介绍了羧酸气相催化酮化合成酮的反应过程,以反应所涉及的关键影响因素如催化剂、反应物和反应温度等为对象,系统综述了羧酸气相催化酮化反应的国内外研究进展,对反应机理的研究成果进行了归纳,并指出了将该反应予以推广的必要性,探讨了该反应未来的发展方向。
In this paper, the process for catalytic ketonization of carboxylic acid vapor over catalysts to produce ketones is described. Its progress at home and abroad is summarized systematically, including the key influencing factors such as catalysts, reactants and reaction temperature, and reaction mechanism. The study fruits for its mechanism are summarized, and the development trend is also discussed. Finally, it is pointed out that it is necessary to popularize this method.
出处
《现代化工》
EI
CAS
CSCD
北大核心
2008年第9期22-26,共5页
Modern Chemical Industry
基金
国家高技术研究发展计划('863'计划)资助项目(2006AA06Z369)
关键词
羧酸
催化酮化
合成
酮
carboxylic acid
catalytic ketonization
synthesis
ketones