摘要
目的合成偶氮四唑的固态配合物,研究其液相生成反应的热动力学。方法用RD496-CK2000微热量计测定其液相生成反应焓变。结果制备了6种固态含能配合物M(ATZ)(phen)2.nH2O(M=Mn,n=5;M=Co,Ni,n=2;M=Cu,Pb,n=1;M=Zn,n=3;ATZ=5,5′-偶氮四唑,phen=1,10-邻菲啰啉),计算出了它们的液相生成反应的热动力学参数。结论反应条件温和,其液相生成反应焓变均为负值,有利于常温反应。
Aim To Synthesize and characterize solid energetic complexes, and study thermokinetics of liquidphase reaction at various temperatures. Methods The enthalpy changes of liquid phase reaction, △ArHm^θ, were investigated using an RD496-CK2 000 microcalorimeter. Results Six solid energetic complexes M （ATZ） （Phen）2 nH2O （ M = Mn, n = 5 ; M = Co, Ni, n = 2 ; M = Zn, Pb, n = 1, M = Zn, n = 3 ; ATZ = 5,5＇-azotetrazolate, phen = 1,10 phenothroline） were prepared. In addition, thermokinetic parameters of liquid-phase reactions are calculated. Conclusion All the values of △ArHm^θ are negative, which indicates that the exothermic effects more favor these reactions.
出处
《西北大学学报（自然科学版）》
CAS
CSCD
北大核心
2008年第4期597-601,共5页
Journal of Northwest University（Natural Science Edition）
基金
国家自然科学基金资助项目(20771089)
陕西省自然科学基金资助项目(2007B02)
关键词
含能配合物
液相生成反应
热动力学
energetic complex
liquid phase reaction
thermokinetics
