摘要
在七（２，６－二－０－正戊基－３－０－三氟乙酰基）－β-环糊精（ＤＰ－ＴＦＡ－β-ＣＤ）手性固定相上 分离除虫农药菊酸乙酯，顺式菊酸乙酯可达到基线分离，反式可达到半高峰宽以下分离，证明 为一种较好的固定相，并从热力学角度探讨了其分离机理。
Ethyl chrysanthemate was separated on heptakis (2, 6-di-O-Pentyl-3-O-tri- fluroacetyl)-β-cyclodextrin (DP-TFA-β-CD ). The cis-isomer can be baseline-separated, while the trans isomer is only half-peak-height-separated. It demonstrates that DP-TFA-β- CD is a good chiral stationary phase. Meanwhile the separation mechanism was discussed from the view point of thermodynamics.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1997年第11期1282-1284,共3页
Chinese Journal of Analytical Chemistry
