摘要
在四氟硼酸银存在下，分别以硫醚、硫醇、硫酚或过硫醚为原料与碘甲烷反应制备了相应的甲基锍盐。用１ＨＮＭＲ和１３ＣＮＭＲ表征产物的结构并提出了反应的机理。
In the presence of silver tetrafluoroborate, sulfides,thiols,thiophenols and disulfides reacted with methyl iodide to form correspounding methylsulfonium salts at room temperature. The chemical shifts of 1H NMR and 13 C NMR of added methyl groups are given and the reaction mechanisms are proposed.
出处
《合成化学》
CAS
CSCD
1997年第4期362-367,共6页
Chinese Journal of Synthetic Chemistry
基金
煤炭系统回国留学人员科技基金
关键词
甲基铳盐
硫醚
硫醇
硫酚
过硫醚
铳盐
Methylsulfonium salts, Sulfides, Thiols, Thiophenols, Disulfides, Methyl iodide.
