摘要
采用溶胶-凝胶法在石英玻璃衬底上制备了Al/Zn原子比为0.1%的ZnO:Al薄膜,在500℃的氩气中进行了1~5h不同时间退火处理,利用X射线衍射(XRD)、光致发光(PL)、透射光谱和四探针法研究了退火时间对薄膜性能的影响。结果显示,退火1h时,样品出现了C轴择优取向,深能级发射(DLE)提高,可见光区光学透过率约为80%,电阻率仅为4×10^-2Ω·cm。更长时间退火后,随着退火时间增加,薄膜结晶质量逐渐变差,电阻率逐渐增大。
ZnO : Al thin films doped with 0.1% aluminum(Al/Zn=0.1%) were deposited on quartz glass by the sol-gel technique. The as-prepared sample is annealed in argon ambient at 500 ℃ and annealing time is varied between 1 and 5 h. The effects of different annealing time on the properties of ZnO: Al thin films were investigated by X-ray diffraction(XRD), photoluminescence (PL), optical transmittance and four-probe method. Results show that when annealing time is 1 h, the sample exhibits preferred c-axis orientation, DLE is enhanced, the optical transmittances is about 80% in the visible region and the resistivity of the sample is only 4×10^-2 Ω· cm. When annealing time exceeds 1 h, the crystal quality becomes poor and the resistivity is increased continuously with increasing annealing time.
出处
《半导体光电》
EI
CAS
CSCD
北大核心
2008年第4期548-552,共5页
Semiconductor Optoelectronics
基金
高等学校博士点科研基金资助课题(20050614013)
教育部新世纪优秀人才支持计划资助课题(NCET-04-0899)