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离子对缔合聚合物溶液黏度剪切保留率影响研究 被引量:10

Effect of ion on viscosity shear retention rate of associating polymer solution
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摘要 针对渤海SZ36-1油田高温、高盐、大井距对注聚用聚合物剪切稳定性的要求,进行了SZ36-1油藏条件下,Na+、K+、Ca2+、Mg2+等离子对缔合聚合物AP-P4溶液黏度剪切保留率的影响研究。研究发现,影响缔合聚合物溶液黏度剪切保留率的关键因素是溶液中的Ca2+、Mg2+;在Na+、K+浓度小于10 000 mg/L时,其存在有益于提高溶液黏度的剪切保留率;Ca2+、Mg2+浓度超过400 mg/L时,溶液黏度的剪切保留率开始明显降低;在Ca2+、Mg2+浓度低于100 mg/L时,其存在有助于提高溶液黏度剪切保留率。在模拟渤海SZ36-1油田注聚水源井A15井的水质条件下,证实了Ca2+、Mg2+是影响缔合聚合物AP-P4黏度剪切稳定性的关键因素。 The characteristics of high temperature, high salt and wide well spacing in Bohai SZ36-1 oil field request good shear stability of injected polymer. Under reservior conditions, a.study was carried out on how the ion (including Na^+, K^+, Ca^2+ and Mg^2+) affected viscosity shear retention rate of associating polymer AP-P4 solution. It is found that the key element is Ca^2+ and Mg^+2+ in the solution. Existence ofNa^+ and K^+ can enhance shear retention rate when concentration is 〈 10,000mg/L. Viscosity shear retention rate starts obviously to reduce when concentration of Ca^2+ and Mg^2+ is 〉 400mg/L ,while Ca^2+ and Mg^2+ can enhance shear retention rate when concentration is 〈 100 mg/L. Simulating water quality of the water source well A15 in the Bohai SZ36-1 oil field, it has been confirmed that Ca^2+ and Mg^2+ in the solution are the key factors to affect the viscosity shear stability of association polymer AP-P4.
出处 《石油钻采工艺》 CAS CSCD 北大核心 2008年第4期96-99,共4页 Oil Drilling & Production Technology
基金 国家"十一五"863项目"渤海油田聚合物驱提高采收率技术研究"(编号:2007AA090701)资助
关键词 渤海油田 缔合聚合物 黏度 剪切保留率 阳离子 影响因素 Bohai Oil field associating polymer ,viscosity, shear retention rate, cations influencing factors
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  • 1[6]Aubry T,Moan M.Oil & gas science technology hydrophobically associating polymers as rheology modifiers[J].1997,52(2):129-132.
  • 2[8]Juntao Ma,Bin Liang,Ping Cui,et al.Dilute solution properties of hydrophobically associating polyacrylamide:fitted by different equations[J].Polymer,2003,44 (4):1281-1286.
  • 3McCormick C L,Bock J,Schulz D N.Water-soluble polymer[A].in:Mark H F.Encyclopedia of polymer science and engineering[C].New York:Wiley-Interscience,1989.730-784.
  • 4冯玉军.疏水缔合水溶性聚合物溶液结构及其对溶液流变性影响的研究[D].西南石油学院博士论文,1999.
  • 5韩丽娟.油气开采用水溶性聚合物的研究[D].西南石油学院博士论文,2004.
  • 6Hill A,Candau F,Selb J.Aqueous solution properties of hydrophobically associating copolymers[J].Progress in Colloid &Polymer Science,1991,84:61-65.
  • 7Vittadello S T.Biggs S.Shear history effects in associative thickener solutions[J].Macromolecules,1998,31:7 691-7 697.
  • 8Jean-Francois Le Meins,Jean-Francois Tassin.Shear-Induced phase separation in an associating polymer solution[J].Macromolecules,2001,34:2 641-2 647.
  • 9Joseph Selb,Simon Biggs,Delphine Renoux,et al.Hydrophobic and electrostatic interactions in water-soluble associating copolymers[A].In:Glass J E.Hydrophobic polymers:performance with environmental acceptance[C].Advances in Chemistry Series 248,American Chemical Society,Washing DC,1996,251-278.
  • 10Salazar L C,McCormick L.Copolymers of acry-lamide and a novel sulfobetaine amphoteric monomer[A].In:Shalaby S W,McCormick C L,Butler G B.Water-soluble polymer:synthesis,Solution Properites and Applications[C].ACS Symp.Ser.467,American Chemical Society,Washington DC,1991.119-129.

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