摘要
本文从非优先溶剂化和一定量溶液的总自由能G总是固定的观点出发,导出了一个与溶剂化数h有关的活度系数公式: 经实验数据与文献实验数据验证,表明该公式在1<0.1的浓度范围内是成立的。
This paper based on the view point of non-prefer solvation and from the theory of the total Gibbs free energy G is always constant in a fixed quantity of solution,no matter whether solvated or not , get a activity coefficient formula:We use the formula correlated the exprimental data, the results show that it is approximately suited when the electrolyte concentration I<0.1N.
出处
《河南大学学报(自然科学版)》
CAS
1990年第2期89-94,共6页
Journal of Henan University:Natural Science
关键词
混合溶剂
活度系数
电解质
溶液
mixed solvepts, activity coef f icient,solvated number.