摘要
原子转移自由基聚合是一种新的活性自由基聚合方法。研究了氯乙腈／氯化亚铜／２，２＇－联吡啶引发的苯乙烯本体聚合反应，考察了单体转化率与相对分子质量之间的关系，并初步探讨了聚合反应动力学。
Atom transfer radical polymerization is a new type of living radical polymerization method. In this paper the bulk polymerization of styrene is initiated by chloroacetonitrile/copper(Ⅰ)chloride/2,2-bipyridine initiating system. The polymerization kinetics and the relations between monomer conversion and molecular weight and its distribution have been studied.
出处
《北京化工大学学报（自然科学版）》
CAS
CSCD
1997年第3期26-29,共4页
Journal of Beijing University of Chemical Technology(Natural Science Edition)
关键词
原子转移
自由基聚合
苯乙烯
分子质量
引发剂
atom transfer radical polymerization
living polymerization
styrene
molecular weight distribution
