摘要
综述了非茂单活性中心过渡金属催化剂在催化烯烃配位活性聚合领域里近年来的研究进展,重点介绍了能够催化烯烃活性聚合的前过渡金属Ti,Zr及后过渡金属Ni,Pd,Co的催化剂的结构及催化烯烃活性聚合的特点。同时,也对非茂过渡金属催化剂能够催化烯烃活性聚合的原因做了一定的探讨。
Advance in the living olefin polymerization using non - metalloeene transition metal catalysts has been reviewed. In this paper, the structures of two kinds of non - metalloeene transition metal catalysts including early transition metal Ti, Zr, late transition metal Ni, Pd, Co and their characters of living olefin polymerization have been introduced. In addition, the reason of living polymerization has been discussed.
出处
《中山大学研究生学刊（自然科学与医学版）》
2008年第1期29-39,共11页
Journal of the Graduates Sun YAT-SEN University(Natural Sciences.Medicine)
关键词
过渡金属
催化剂
烯烃
活性聚合
Transition metal
Catalysts
Olefin
Living polymerization
