摘要
本文合成了氧心羧桥二种铁配合物：［Ｆｅ３Ｏ（Ｃ６Ｈ５ＣＯＯ）６（Ｈ２Ｏ）３］Ｃｌ和［Ｆｅ４Ｏ２（Ｃ６Ｈ５ＣＯＯ）７（ｂｉｐｙ）２］ＣｌＯ４，测定了它们的热失重及相应热效应峰值的红外光谱。根据不同温度下红外光谱基团的特征吸收峰的变化及热失重情况的分析。
The title complexes shown as [Fe 3O(C 6H 5COO) 6(H 2O) 3]Cl ·1 5H 2O and [Fe 4O 2(C 6H 5COO) 7(bipy) 2]ClO 4·3 5H 2O were prepared.Their thermal decomposition process was studied qualitatively and quantitatively by means of thermogravimetric analysis and infrared spectroscopic measurement of samples after heating at different temperatures.From the experimental results,the possible thermal decomposition process of the two compounds can be deduced.Additionally,according to the fact that the ν as (COO) of the two compounds decreases while the ν s(COO ) remains unchanged as the heating temperature increases.It can be drawn that the carboxylate coordinative form possible change from bridged to chelate one.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
1997年第3期42-45,共4页
Spectroscopy and Spectral Analysis
关键词
热稳定性
铁配合物
三核
四核
苯甲酸
Thermal decomposition, Iron complex, Trinuclear complex, Tetranuclear complex
