摘要
介绍了基于温控膦配体的新型液/液两相催化体系温控相转移催化(TRPTC)和温控相分离催化(TPSC)的基本原理。首次将温控膦配体的合成方法进行分类,分为环氧乙烷加成法和醇解反应合成法两大类并分别加以介绍,全面总结了温控膦配体在各类液/液两相催化反应中的应用。
With thermoregulated ligands as main line, the general principles transfer catalysis （TRPTC） and thermoregulated phase- separablecatalysis of thermoregulated phase （TPSC） were introduced, based on thermoregulated ligands. The synthesize method of thermoregulated ligands divided into ethyleneoxide addition and alcoholysis reaction, and introduced respectively. This paper reviewed recently developed examples of thermoregulated ligands in the liquid/liquid two phase catalysis field.
关键词
温控配体
临界溶解温度
液/液两相催化
温控相转移催化
温控相分离催化
thermoregulated ligand
critical solution temperature
liquid/liquid two phase catalysis
thermoregulated phase transfer catalysis
thermoregulated phase- separable catalysis
