摘要
本文自论了在乙醇溶剂中,以三氯化铁同1—苯基—3—甲基—4—(α—呋喃甲酰基)吡唑啉酮—5(HPMaFP)及8—羟基喹啉(HOX)作用,制得两种配合物,并测得它们的组成为Fe(PMaFP)_3和和Fe(PMaFP)(OX)_2。研究了它们的红外光谱、紫外光谱、热稳定性等性质。观察了它们在常见有机溶剂中的溶解情况。在乙腈中的电导测定结果表明,这些配合物均为非电解质。
In this paper, the two coordination compounds of iron three halides with 1-phenyl-3-methyl-4-(α-furoyl)Pyrazolone-5(HPMαFP) and8-hydroxyquinel-ine(HOX)in ethanol medium have been synthesized.The composition of the new coordination compounds have been determined as Fe(PMαFP)_3 and Fe(PMαFP)(OX)_2, and characterized by elementalanalyses, IR and UV spectra, thermogravimetric(TC)and differential thermal analyses(DTA).The solubility behaviour of them in various solvents are obsenved.Furthemore, these compounds are pJoved to be nonelectnolytes by conductance measurement in acetonitrile solution.
出处
《哈尔滨师范大学自然科学学报》
CAS
1990年第2期48-52,共5页
Natural Science Journal of Harbin Normal University
关键词
铁
吡唑啉酮
羟基喹啉
配合物
合成
Iron Pyrazolone 8-hydroxyquineline Coordination compound
