摘要
合成了1个新的双核铜配合物。通过IR、UV-Vis及X射线单晶衍射对其结构进行了表征。测试结果表明:该配合物属单斜晶系,C2/c空间群,a=2.2411(2)nm,b=1.8342(2)nm,c=1.8779(2)nm,β=122.861(2)°,V=6.4843(11)nm3,Z=8,Dc=1.604g/cm3,F(000)=3232,R1=0.0671,wR2=0.1447。配合物中Cu…Cu之间的距离为0.3102nm。
A novel dinuelear copper（Ⅱ） complex, [ Cu2 （C29H36- NsO3） ]ClO4@2H2O·0.5CHaCN, had been synthesized and charaeterized by IR, UV-Vis and singal-erystal X-ray diffraetometry. The results showed that the complex crystals belonged to a monoclinic system, and the space group C2/e had the following parameters： a = 2.241 1（2）nm, b = 1.834 2（2） nm, c = 1.877 9（2） nm,fl= 122.861（2）°, V= 6.484 3（11） nm^3,Z = 8, Dc = 1.604 g/cm^3, F（000） = 323 2, R1 = 0.067 1,and wR2 = 0.144 7. The distance between Cu… Cu in the complex Was 0.516 3 nm.
出处
《化学试剂》
CAS
CSCD
北大核心
2008年第4期285-286,303,共3页
Chemical Reagents
关键词
双酚氧桥联
双核铜配合物
晶体结构
bis（phenoxo） bridged
binuelear copper（ Ⅱ） complex
crystal structure
