摘要
介绍了国内外甲烷临氧催化转化制合成气的研究进展,结合本课题组的研究结果及文献报道,对甲烷部分氧化、甲烷临氧二氧化碳重整、甲烷临氧水蒸气重整及甲烷-二氧化碳-水-氧气耦合三重整反应进行了阐述和分析,综述了在催化剂体系、反应机理和工艺条件等方面取得的近期研究成果。最后对甲烷临氧催化转化制合成气技术今后的研究重点及应用领域作了展望。
In this paper, the research progress of synthesis gas preparation by catalytic conversion of methane in the presence of oxygen is summarized. The authors＇ work in preparing syngas form methane in the presence of oxygen is introduced. Catalytic partial oxidation （CPO）, autothermal CO2 reforming （ATR-CO2）, autothermal HaO reforming （ATR-H2O） and triple-reforming of methane are reviewed. The achievements in catalyst, reaction mechanism and process conditions are also discussed. The research focus and commercial application of catalytic conversion of methane in the future are also prospected.
出处
《化工进展》
EI
CAS
CSCD
北大核心
2008年第4期503-507,共5页
Chemical Industry and Engineering Progress
基金
国家自然科学基金重点资助(20433030)
河南省高校新世纪优秀人才支持计划(2006HANCET-20)
关键词
甲烷
合成气
部分氧化
自热重整
催化
methane
syngas
partial oxidation
autothermalreforming
catalysis
