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钒(Ⅳ)配位超分子的合成、晶体结构及光电性能 被引量：3

Synthesis,structure and photoelectric property of a V(Ⅳ) coordination supermolecule
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摘要 采用水热方法合成了V（Ⅳ）配合物[VO（phen）（C2O4）（H2O）],其结构经单晶X-射线衍射测定.结构分析表明化合物中存在着丰富且相互平行的氢键,从而将配合物分子网联成1D配位超分子.采用表面光电压及场诱导表面光电压技术研究了配合物的光电性能.结果表明,该化合物在300-800 nm范围内有较强的光伏响应,且呈现出P型半导体的特征.此外,讨论了化合物的UV-VIS-NIR及IR光谱. A complex [VO（phen） （C2 04 ）（H2 O）]has been synthesized by hydrothermal method, and its structure determined by single crystal X-ray diffraction. The analysis of structure shows that the complex is a 1D coordination supermolecule constructed by various parallel hydrogen bonds. The photoelectric transfer property was investigated by surface photovoltage spectroscopy （SPS） and field-induced surface photovoltage spectroscopy （FISPS） techniques, and the result reveals that the complex exhibits stronger surface photovoltage （SPV） response in the range of 300-800nm, and possesses the characteristic of p-type semiconductor. In addition, we tentatively discussed the spectroscopies of UV- VIS-NIR and IR.
作者 牛淑云 宫林崇 金晶 张丽 史忠丰
机构地区 辽宁师范大学化学化工学院
出处 《辽宁师范大学学报（自然科学版）》 CAS 北大核心 2008年第1期60-63,共4页 Journal of Liaoning Normal University:Natural Science Edition
基金 国家自然科学基金资助项目(20571037 90201018)
关键词 钒(1V)配住超分子 晶体结构 光电性能 （Ⅳ） coordination supermolecule crystal structures photoelectric property
分类号 O641.33 [理学—物理化学] O641.4 [理学—物理化学]
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参考文献7

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共引文献10

同被引文献32

  • 1张丽,牛淑云,金晶,孙丽萍,杨光第,叶玲.系列Mn(Ⅱ)配位超分子的合成、晶体结构和表面光电压研究[J].化学学报,2007,65(11):1032-1038. 被引量：14
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辽宁师范大学学报（自然科学版）
2008年 第1期

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