摘要
合成了十八种Ｋｅｇｇｉｎ结构稀土元素四元杂多配合物Ｋ１２Ｈ３［Ｌｎ（ＧｅＷ１０ＶＯ３９）２］·ＸＨ２Ｏ和Ｋ１１Ｈ２［Ｌｎ（ＰＷ１０ＶＯ３９）２］·ＸＨ２Ｏ（Ｌｎ＝Ｌａ３＋，Ｃｅ３＋，Ｐｒ３＋，Ｎｄ３＋，Ｓｍ３＋，Ｅｕ３＋，Ｇｄ３＋，Ｄｙ３＋，Ｙｂ３＋）。利用ＴＧ－ＤＴＡ、变温红外光谱、变温Ｘ射线衍射和溶解性实验方法，对配合物的热稳定性进行了研究，讨论了影响热稳定性的因素。
In this paper, eighteen heteropoly complexes of lanthanide with keggin structure have been synthesized. Their thermal stability was studied by TG-DTA, IR spectra, X-ray powder diffraction at various temperatures and solubility experimental method. The factors having influence on the thermal stability were studied.
出处
《化学与粘合》
CAS
1997年第2期74-76,91,共4页
Chemistry and Adhesion
基金
黑龙江省自然科学基金
