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阀控式铅酸蓄电池中的氧循环与热失控现象 被引量:5

The closed oxygen cycle and the phenomenon of thermal runaway in valve-regulated lead-acid batteries
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摘要 研讨了阀控式铅酸蓄电池在充电后期的主要反应和它们的热效应,论证了闭合氧循环在密封电池内通过两个途径实现,它们将大部分电能转化为热能而耗散,在散热不良的状况下,电池温度上升迅速,因自加速效应而会导致热失控现象。因此,对阀控式铅酸蓄电池充电必须严格控制条件以减少正极氧的析出,同时保证必要的散热条件。 The main reactions and their heat effects at the later stage of charge in valve-regulated lead-acid batteries (VRLAB) were studied' It was also discussed that the closed oxygen cycle (COC) in sealed betteries is car-ried out through two ways and most of the electric energy is transformed into heat and is lost in the end. When the heat exchange with the enviro-ment is not good, the cell temperature rises quickly and results in thermal runaway because of the self-accelerating effect. Consequently, it is impor-tant to control the factors to decrease the forming of oxygen during the charge of VRLAB, and a good condition of heat release must be assured at the same time.
机构地区 青岛大学化学系
出处 《蓄电池》 1997年第2期3-7,28,共6页 Chinese LABAT Man
关键词 铅酸蓄电池 闭合氧循环 热效应 热失控 Vavle-regulated lead-acid batteris, Closed oxygen cycle, Heat effect, Thermal runaway
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参考文献1

  • 1[苏]达索扬(М·А·Дасоян),[苏]阿古夫(И·А·Агуф) 著,华寿南.铅蓄电池现代理论[M]机械工业出版社,1981.

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