摘要
Ｃ６０和β－叠氮丙酸在氯苯中回流，产物经柱色谱分离、ＦＤ－ＭＳ证实为五加成Ｃ６０衍生物，１３ＣＮＭＲ、ＦＴ－ＩＲ和ＵＶ光谱对产物结构进行了表征。
Pentakisadduct metacetonic acid C 60 aza derivative was synthesized by reaction of C 60 with β azido metacetonic acid in chlorobenzene at 120℃ under N 2, the product was isolated by column chromatography and was identified by FD MS, UV Vis, FT IR and 13 C NMR spectroscopies.
出处
《合成化学》
CAS
CSCD
1997年第1期107-108,共2页
Chinese Journal of Synthetic Chemistry
关键词
合成
加成反应
氮杂丙酸
碳60衍生物
C 60 derivative, Synthesis, Addition reaction, Azide metacetonic acid.
