期刊文献+

低温烧结Ba_3Ti_5Nb_6O_(28)陶瓷及其微波介电性能 被引量:3

Low Temperature Sintering and Microwave Dielectric Properties of Ba_3Ti_5Nb_6O_(28) Ceramic
在线阅读 下载PDF
导出
摘要 研究了CuO助剂对Ba3Ti5Nb6O28陶瓷的烧结特性、微结构以及介电性能的影响。研究表明,适量CuO助剂能使Ba3Ti5Nb6O28陶瓷的烧结温度从1 300℃降到950℃以下。部分CuO会固溶于Ba3Ti5Nb6O28并改变其晶粒形状,出现少量长条状晶粒。随着CuO含量增加,介电常数(rε)无明显变化,品质因数与频率之乘(Q×f)值因固溶物的产生而下降,频率温度系数(τf)向负频率温度系数方向移动。w(CuO)为1%的Ba3Ti5Nb6O28样品,在920℃、2 h下,获得了介电性能较好的低温共烧陶瓷,其介电常数rε为41,Q×f=6 500 GHz,τf=4×10-6/℃。 Effects of CuO assistants on densification, microstructure and microwave dielectric properties of Ba3Ti5Nb6O28 ceramics have been investigated. The densification temperature of Ba3Ti5Nb6O28 is greatly reduced from 1 300℃ down to 950℃ with a bit amount of CuO. The shape of grains were changed because of CuO doping Ba3Ti5Nb6O28 and some elongated grains appeared. Increasing the amount of CuO, εr changed slightly, while Q×f decreased because of solid solution and rf move towards negative. A kind of low temperature co-fired ceramic was obtained by sintering at 920℃ with the addition of 1% CuO and showed good dielectric properties.,εr =41 ,Q×f= 6 500 GHz,τf=4×10^-6/℃.
出处 《压电与声光》 CSCD 北大核心 2008年第1期84-86,89,共4页 Piezoelectrics & Acoustooptics
关键词 低温共烧 CUO 微波介电性能 low temperature co-fired CuO microwave dielectric properties
  • 相关文献

参考文献13

  • 1曲远方.功能陶瓷及应用[M].北京:化学工业出版社,2002:300-317.
  • 2HUANG Chen-liang, CHEN Yao-chung. Microwave dielectric properties and microstructure of Ba2-x Sm4-2x/3Ti8+y O24+2y[J]. Mater Sci Eng, 2003, A345 (1-2) :106-112.
  • 3CHRISTOFFERSEN R, DAVIES P K. Effect of Sn substitution on cation ordering in (Zr1-x Snx ) TiO4 microwave dielectric ceramics[J]. J Am Ceram Soc, 1994,77 (6):1441-1450.
  • 4PARK J K, KIM D Y. Effect of grain size on diffusion-induced grain-boundary migration in Ba (Zn1-3 Nb2-3)O3 ceramics[J]. J Am Ceram Soc, 1996, 79 (5): 1405-1408.
  • 5MILLET J M, ROTH R S, ETTLINGER L D, et al. Phase equilibria and crystal chemistry in the ternary system BaO-TiO2-Nb2O5,[J]. J Solid State Chem, 1987, 67(2) :259-270.
  • 6ROBERTS G L, CAVA R J, PECK W F, et al. Dieletric properties of barium titanium niobates[J]. J Mater Res, 1997, 12(2):526-530.
  • 7RATHEESH R, SREEMOOLANADHAN H, SU- MA S, et al. New high permittivity and low loss ceramics in the BaO-TiO2-Nb2O5 composition [J]. J Mater Sci: Mater Electron, 1998, 9(4):291-294.
  • 8SEBASTIAN M T. New low loss microwave dielectric ceramics in the BaO-TiO2-Nb2O5/Ta2O5 system[J]. J Mater Sci: Mater Electron, 1999, 10(7) :475-478.
  • 9FANG Liang, ZHANG Hui, QING Lin-qin, et al. Synthesis and X-ray powder study of a new compound: Ba6 Ti7 Nb9 O42 [J]. J Wuhan Univ Tech, 1998,13(4):42-44.
  • 10ZAJC I, DROFENIK M. Preparation of PTCR ceramics in the BaO-TiO2-Nb2O5 system[J]. J Eur Ceram Soc, 1999, 19(6-7):893-896.

同被引文献30

  • 1蔡绍,徐国跃,翁履谦,凌栋.BaTi4O9微波介质陶瓷的低温烧结[J].功能材料,2004,35(z1):1512-1514. 被引量:1
  • 2丁士华,姚熹,张良莹,楼旭东.片式多层陶瓷微波谐振器[J].压电与声光,2004,26(4):280-282. 被引量:1
  • 3王茹玉,黄金亮,周焕福,殷镖,孙道明,赵高磊.CuO掺杂对ZnNb_2O_6介质陶瓷性能的影响[J].材料导报,2005,19(11):125-127. 被引量:3
  • 4TAKADA T, WANG S F, YOSHIKAWA S, et al. Effects of glass additions on (Zn, Sn)TiO for micro-wave applications[J]. J Am Ceram Soc, 1994,77 (9) 2485-2488.
  • 5TAKADA T, WANG S F, YOSHIKAWA S, et al. Effects of glass additions on BaO-TiOz-WOa for mi-crowave ceramics[J]. J Am Ceram Soc, 1994,77 (7) :1909-1916.
  • 6ICHINOSE N,YAMAMOTO H. Effect of additives on microwave dielectric properties in low-temperature fir- ing (Mg, Ca)TiO3 based ceramics[J]. Frrroelrctrics, 1997,201(1) :255-262.
  • 7OKAWA T,IMAEDA M,OHSATO H. Microwave di- electric properties of Bi-added Ba4 Ndg-i a Ti18O51 solid solutions[J]. Jpn J Appl Phys, 2000,39(9B):5645- 5649.
  • 8KIM H T,KIM S H,NAHM S,et al. Low-temperature sintering and microwave dielectric properties of zincmetatitanate-rutile mixtures using boron[J]. J Am Ce- ram Soc, 1999,82(11 ) :3043-3048.
  • 9LEE Y C,LEE W H,SHIEU F S. Effects of B2O3 ad- dition on the microwave dielectric properties ofBazTigO20 ceramics[J]. Jpn J Appl Phys,2003,42(3) : 1311-1314.
  • 10KIM J R,KIM D W,YOON S H,et al. Low tempera- ture sintering and microwave dielectric properties ofBa3 Ti5 Nb6 O28 with B2 O3 and CuO additions[J] J Elec- troceram, 2006,17 (2) : 439-443.

引证文献3

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部