摘要
采用Ｂａｒｋｅｒ－Ｈｅｎｄｅｒｓｏｎ软核微扰理论的方法改进马丁－侯状态方程，在“多方阱”微扰势的基础上引入一简单的“软排斥”势，导出了方程体积参数ｂ与温度的函数关系以及新的常数的计算公式。使马丁－侯方程各参数的物理意义得到进一步解释，初步计算表明改进后的马丁－侯方程的计算精确度有所提高。
Barker and Henderson′s soft core perturbation theory is used to improve the Martin Hou equation of state. In addition to multi square well perturbation potential a soft repulsion reference potential is employed and an approximate expression of soft core diameter as a function of temperature is obtained. The results calculated from the equation of state are in good agreement with experimental data.
出处
《高校化学工程学报》
EI
CAS
CSCD
北大核心
1997年第1期15-19,共5页
Journal of Chemical Engineering of Chinese Universities
基金
浙江省自然科学基金
关键词
状态方程
微扰理论
软核
马丁-侯
Equation of state, Perturbation theory, Soft core
