摘要
通过重氮化、偶合、还原和烷基化反应合成了7个I型苯并三唑类紫外线吸收剂,并经红外光谱、质谱、元素分析等手段确证结构,其中6个为新化合物。对所合成的紫外线吸收剂进行了紫外-可见光谱测试,发现所有I型苯并三唑类紫外线吸收剂皆有优良的紫外吸收能力,摩尔消光系数是Ⅰ型紫外线吸收剂Seesorb708的1.55~1.68倍。
Seven type II UV absorbers of benzotriazol structure were prepared by diazotization,coupling,reduction and alkylation.Their structures were characterized by IR,MS and elem entary analysis.Six of them were new compounds.The UV V is absorption of those UV absorbers was tested.All those compounds were found to have good absorption ability of UV light,and were found to have 1.55~1.68 times absorption ability of Seesorb 708(type Ⅰ)absorbers.The relation between absorption and molecule structure was also stated.
出处
《华东理工大学学报(自然科学版)》
CAS
CSCD
北大核心
1997年第3期321-326,共6页
Journal of East China University of Science and Technology
关键词
紫外线吸收剂
苯并三唑
间苯二酚
烷基化
合成
ultraviolet absorber
photostabilizer
benzotriazole
1,3 dihydroxybenzene
alkylation