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Ⅱ型苯并三唑类紫外线吸收剂的合成 被引量:11

Synthesis of Type II UV Absorbers of Benzotriazol Structure
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摘要 通过重氮化、偶合、还原和烷基化反应合成了7个I型苯并三唑类紫外线吸收剂,并经红外光谱、质谱、元素分析等手段确证结构,其中6个为新化合物。对所合成的紫外线吸收剂进行了紫外-可见光谱测试,发现所有I型苯并三唑类紫外线吸收剂皆有优良的紫外吸收能力,摩尔消光系数是Ⅰ型紫外线吸收剂Seesorb708的1.55~1.68倍。 Seven type II UV absorbers of benzotriazol structure were prepared by diazotization,coupling,reduction and alkylation.Their structures were characterized by IR,MS and elem entary analysis.Six of them were new compounds.The UV V is absorption of those UV absorbers was tested.All those compounds were found to have good absorption ability of UV light,and were found to have 1.55~1.68 times absorption ability of Seesorb 708(type Ⅰ)absorbers.The relation between absorption and molecule structure was also stated.
出处 《华东理工大学学报(自然科学版)》 CAS CSCD 北大核心 1997年第3期321-326,共6页 Journal of East China University of Science and Technology
关键词 紫外线吸收剂 苯并三唑 间苯二酚 烷基化 合成 ultraviolet absorber photostabilizer benzotriazole 1,3 dihydroxybenzene alkylation
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参考文献3

  • 1黄瑞鑫,世界精细化工产品质量标准汇编,1989年
  • 2Li Shanjun,Monatshefts Chem,1984年,115卷,6/7期,853页
  • 3Li Shanjun,Monatshefts fur Chemie,1983年,114卷,8期,937页

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