摘要
使NiSO4.6H2O与4,4′-联吡啶(4,4′-bipy)在甲醇和水的混合溶剂中反应,合成了一个配位聚合物{[Ni(4,4′-bipy)2(H2O)4](SO4).2H2O}n。结构测试表明,在此配合物中,Ni(Ⅱ)通过多个有机含氮配体桥连形成了一个无限的长链结构。研究了这个配合物的热稳定性能。
The coordination polymer { [ Ni （4,4＇ - bipy） 2 （ H2O ） 4]（ SO4 ） ·2 H2O} is prepared through the reaction of NiSO4·6H2O with 4,4＇ -bipyridine in the solution of methanol and water. The structure of the complex is confirmed by X - ray structural diffraction, elemental analysis and IR data. In the complex,the Ni（ Ⅱ ） ions are connected by 4,4＇ - bipyridine forming one - dimensional chain. The thermal property of the compound is determined.
出处
《河南化工》
CAS
2007年第12期31-33,共3页
Henan Chemical Industry
