摘要
研究了2，2-双（3-烯丙基-4-羟基苯基）六氟丙烷的合成工艺．以六氟双酚A、溴丙烯和无水碳酸钾为原料，N，N-二甲基甲酰胺为溶剂，在100℃下反应12h，得到六氟双酚A二烯丙基醚（Ⅰ）。经提纯后，使其在200℃回流8h，经碱洗、萃取、分液、酸化得到目标产物2，2-双（3-烯丙基-4-羟基苯基）六氟丙烷（Ⅱ），总收率58．2％．用红外光谱和核磁共振氢谱对产物的结构进行了表征．
Diallyl ether of hexafluorobisphenol A （Ⅰ） was prepared from hexafluorobisphenol A, allylbromid and anhydrone potassium carbonate at 100℃ for 12 h in DMF. After purification, the intermediate I refluxed at 200℃ for 8 h. By washing with sodium hydroxide, extracting with dicholomethane, separating and acidification by hydrochloric acid, the needed product of 2, 2-bis （3-allyl-4-hrdroxyphenyl） （Ⅱ） was obtained. Total yield of this procedure reached 58.2%. Structure of the product Ⅱ was identified by IR and ^1HNMR.
出处
《功能材料》
EI
CAS
CSCD
北大核心
2007年第A07期2694-2695,共2页
Journal of Functional Materials
