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多面体低聚硅倍半氧烷的研究进展 被引量:1

Process in the synthesis of polyhedral oligomeric silsesquioxane
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摘要 综述了多面体低聚硅倍半氧烷(POSS)的结构特性和合成方法,重点介绍了同取代基、单官能度、双官能度、多官能度四类POSS的合成方法,比较了各种合成方法的优劣,展望了POSS合成研究的发展方向。 The structures,properties and synthesis of polyhedral oliogmeric silsesquioxane(POSS) are reviewed.In particular the synthesis of homo-POSS,monofunctional,difunctional,mulfunctional POSS were introduced.The disadvantages and advantages of each methods were analyzed and future development of POSS was proposed
出处 《有机硅材料》 CAS 2007年第6期354-359,共6页 Silicone Material
基金 湖北省自然科学基金(2005ABA034) 湖北省催化材料重点实验室基金(CHCL06003)。
关键词 多面体低聚硅倍半氧烷 合成 单官能度 双官能度 多官能度 POSS,synthesis,monofuction,difunctional,mulfunctional
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  • 1BANEY R H, ITOH M, SAKSKIBARA A. et al. Silsesquioxanes [J]. Chem Rev, 1995, 95 (5): 1409-1430.
  • 2SCOTF D W. Thermal rearrangement of branchedchain methylpolysiloxanes[J].J Am Chem Soc, 1946, 68 (3): 356-358.
  • 3BROWN J F, VOGT J H. The polycondensation of cyclohexylsilanetriol [J]. J Am Chem Soc, 1965, 87:4313-4317.
  • 4LICHTENHAN J D. Linear hybrid polymer building blocks: methacrylate-functionalized polyhedral oligomeric silsesquioxane monomers and polymers [J]. Macromolecules, 1995, 28: 8435-8437.
  • 5LICHTENHAN J D. Investigations into structure property relationships for polyhedral oligomeric silsesquioxane (POSS) based methacrylate polymers [J].Amer Chem Soc Polym Prep, 1997, 38 (1) : 518-519.
  • 6HADDAD T S, LICHTENHAN J D. Hybrid organic-inorganic thermoplastics: styryl-based polyhedral oligomeric silsesquioxane polymers [J].Macromolecules, 1996, 29 (22) : 7302- 7304.
  • 7MEHL G H, SAEZ I M. Polyhedral liquid crystal silsesquioxanes[J]. Appli Organometal Chem, 1999, 13 (4): 261-272.
  • 8FRAILE J M, GARCIA J I, MAYORAL J A, et al. Catalytic sites in silica-supported titanium catalysts: silsesquioxane complexes as models[J]. J Cataly, 2005, 233 (1) : 90-99.
  • 9HATTON B D, LANDSKRON K, WHITNAL W L, et al. Spin coated periodic mesoporous organosilica thin films-towards a new generation of low-dielectric-constant materials [J]. Adv Func Mater, 2005, 15 (5) : 823-829.
  • 10CHOU C, HSU S, DINAKARAN K, et al. Synthesis and characterization of luminescent polyfluorenes incorporating side-chain-tethered polyhedral oligomeric silsesquioxane units[J]. Macromole cules, 2005, 38 (3) : 745-751.

二级参考文献108

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同被引文献31

  • 1刘长军,田丰,陈世谦,张彦军,刘圣军.有机-无机杂化纳米结构体——多面体低聚硅倍半氧烷研究进展[J].中国塑料,2005,19(9):13-19. 被引量:4
  • 2姚旭霞,李齐方,沈之荃.多面齐聚硅倍半氧烷研究进展[J].化学通报,2006,69(3):161-167. 被引量:9
  • 3MARKOVIC E, CLARKE S, MATISONS J, et al. Poly (ethylene glycol) octafunetionalized polyhedral ol- igomeric silsesquioxane: synthesis and thermal analysis[J]. Maeromoleeules, 2007, 40:2694 -2701.
  • 4VORONKOV M G, LAVRENT'yev V I. Polyhedral oligosilsesquioxanes and their homo derivatives [ J ]. Topics in Current Chem, 1982, 102:199 -236.
  • 5XU H, KUO S, HUANG C, et al. Charaeterization of poly (vinyl pyrrolidone-co-isobutylstyryl polyhedral oligomeric silsesquioxane ) nanocomposites [ J ]. J of Applied Polym Sci, 2004, 91 : 2208 -2215.
  • 6CHEN W, WANG Y, KUO S, et al. Thermal and dielectric properties and curing kinetics of nanomaterials formed from poss-epoxy and meta-phenylenediamine [ J]. Polymer, 2004, 45 (20) : 6897 - 6908.
  • 7HE C, XIAO Y, HUANG J, et al. Highly efficient luminescent organic clusters with quantum dot-like prop- erties [J]. J Am Chem Soc, 2004, 126 (25) : 7792 - 7793.
  • 8ZHANG C, BABONNEAU F, BONHOMME C, et al. Highly porous polyhedral silsesquioxane polymers. synthesis and characterization [ J]. J Am Chem Soc, 1998, 120 (33): 8380-8391.
  • 9STRACHOTA A, TISHCHENKO G, MATEJKA L, et al. Chitosan-oligo (silsesquioxane) blend mem- branes : preparation, morphology, and diffusion permea- bility [ J ]. J of Inorganic and Organometallic Polym, 2001, 11 (3): 165-182.
  • 10r HU Y, SCHIRALDI D A, HILTNER A, et al. Structural model for oxygen permeability of a liquid crystalline [ J]. Macromolecules, 2003, 36 (10) : 3606 - 3615.

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