摘要
采用低热固相化学反应法,一步制备了表面包覆SiO_2的硬脂酸相变储能纳米粒子。由红外光谱、X射线衍射和差示扫描量热法对表面包覆SiO_2的硬脂酸纳米粒子进行了表征。利用动态光散射激光力度仪测定了材料的粒径分布,同时对材料表面包覆前后的接触角进行了测定。结果表明:硬脂酸纳米粒子表面成功包覆了SiO_2层。包覆的硬脂酸纳米粒子为球状,粒径大约为110nm。包覆的硬脂酸纳米粒子相转变温度为61.4℃,相变过程中的焓值为153.1J/g,具有良好的蓄热能力,可用于太阳能利用等方面的储能蓄热。
The synthesis of SiO2 coated stearic acid （SA） nanoparticles via one-step, low heating temperature solid-state chemical reaction is reported. Analytical results of infrared spectroscopy and X-ray diffraction indicate that the SA was coated with a layer of SiO2. The morphology revealed by scanning electron microscopy suggests that the samples were comprised of sphere-like nanoparticles with an average diameter of about 110 nm. The particle size distribution of the samples and the contact angles were determined by dynamic light scattering and a contact angle system. The as-prepared samples were studied with differential scanning calorimetry. The phase transformation temperatures is 61.4 ℃ and the fusion enthalpy is 153.1 J/g. The results show that the samples possess reasonable thermal properties as phase change materials for latent heat storage.
出处
《硅酸盐学报》
EI
CAS
CSCD
北大核心
2007年第11期1430-1433,共4页
Journal of The Chinese Ceramic Society
基金
国家自然科学基金(50676033)资助项目。
关键词
固相反应
脂肪酸
纳米材料
相变材料
复合材料
solid-state reaction
fatty acid
nanomaterials
phase change materials
composite
