摘要
用循环伏安法研究了氯合四-间甲基卟啉铁［Fe（Ⅲ）T（m－CH3）PPCl］，间位取代四苯基卟啉锌［Zn（Ⅱ）T（m—x）PP，x＝CH3，H，OCH3，Cl，NO2］的电化学性质，研究了取代基效应，轴向配体影响以及电子转移速率常数．着重讨论了轴向配体与Fe（Ⅲ）T（m－CH3）PPCl竞争配位的反应机理．
lectrochemical characterization of Zn (Ⅱ ) T (m - x)PP (x ＝-CH3, - H, -OCH3, -Cl, - NO2) and Fe (Ⅲ ) T (m-CH3 ) PPCl were investigated by the technique of cyclicvoltammetry. The effect of substituents on the electrode reaction of Zn(Ⅱ) T(m-x) PP,the effect of axial ligands on the electrode reaction of Fe (Ⅲ) T (m-CH3)PPCl, and thestandard rate constant of electron transfer have been studied. The mechanism of competition coordination of axial ligands with Fe(Ⅲ )T(m-CH3)PPCl were discussed emphasisly.
出处
《南开大学学报（自然科学版）》
CAS
CSCD
北大核心
1997年第2期69-75,共7页
Acta Scientiarum Naturalium Universitatis Nankaiensis
基金
国家自然科学基金
天津市自然科学基金
南开大学吸附分离功能高分子材料国家重点实验室资助
关键词
轴向配位反应
金属卟啉
循环伏安法
锌卟啉
Zn(Ⅱ)T(m-CH_3)PP； Fe(Ⅲ)T(m-CH_3)PPCl
cyclic voltammetry
axial coordination reaction
standard rate constant of electron transfer
