摘要
Study of the phase chemistry relation of quaternary system system CsBr-SmBr3-(13%)HBr-H2O at 25 ℃ is carried out in order to investigate the reaction of CsBr and SmBr3 in hydrobromic acid. A new compound 5CsBr.2SmBr3.22H2O is discovered and obtained in the system. X-ray powder diffraction, thermal analysis (TG and DTA) and polarization character of the new compound obtained from the system are investigated.Meanwhile, the synthetic mechanisms of compounds (CsSm2Br7, Cs3Sm2Br9, Cs3SmBr6 and Cs2SmBr5) are suggested on the basis of phase chemical relation of the system.
Study of the phase chemistry relation of quaternary system system CsBr-SmBr3-(13%)HBr-H2O at 25 ℃ is carried out in order to investigate the reaction of CsBr and SmBr3 in hydrobromic acid. A new compound 5CsBr.2SmBr3.22H2O is discovered and obtained in the system. X-ray powder diffraction, thermal analysis (TG and DTA) and polarization character of the new compound obtained from the system are investigated.Meanwhile, the synthetic mechanisms of compounds (CsSm2Br7, Cs3Sm2Br9, Cs3SmBr6 and Cs2SmBr5) are suggested on the basis of phase chemical relation of the system.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1997年第2期169-173,共5页
Acta Physico-Chimica Sinica
基金
国家自然科学基金
关键词
四元体系
溴化铯
三溴化钐
氢溴酸
固相反应
Quaternary system, Cesium bromide, Samaric tribromide, Hydrobromic acid, Synthesizing mechanism
