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乙醛酸与水杨醛在Cu-Hg阴极上的电解合成 被引量:1

ELECTROLYTIC SYNTHESIS OF GLYOXYLIC ACID AND SALICYLALDEHYDE AT THE Cu-Hg CATHODE
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摘要 选用便于操作的固态Cu-Hg合金作阴极,对草酸与水杨酸进行恒电位电解.电解电流效率均达到55.0~60.0%. The electrolytic reduction of Oxalic and salicylic acids to the corresponding aldehyes was researched many times by the polarography.It was showed by those experiment that the reduction reactions are irresersible at Hygcathode,reduction potential was -1.60V^-1.70V(vs.SCE).Glyoxylic Acid and Salicylaldehyde was obtained by electrolytic synthesis at the Cu-Hg cathode.the current efficiency was 55.0~60.0%.
出处 《南开大学学报(自然科学版)》 CAS CSCD 北大核心 1997年第1期110-112,共3页 Acta Scientiarum Naturalium Universitatis Nankaiensis
关键词 乙醛酸 水杨醛 铜汞合金 阴极 电解合成 合成 Glyoxylic Acid:salicylaldehyde polarography overvotage Cu-Hg cathode electrolytic ynthesis
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  • 1F. Goodridge,K. Lister,R. E. Plimley,K. Scott. Scale-up studies of the electrolytic reduction of oxalic to glyoxylic acid[J] 1980,Journal of Applied Electrochemistry(1):55~60

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